Rhodium phosphines partnered with the carborane monoanions [CB11H6Y6]- (Y = H, Br). Synthesis and evaluation as alkene hydrogenation catalysts

Adem Rifat; Nathan J. Patmore; Mary F. Mahon; Andrew S. Weller

doi:10.1021/om020077r

Rhodium phosphines partnered with the carborane monoanions [CB₁₁H₆Y₆]^- (Y = H, Br). Synthesis and evaluation as alkene hydrogenation catalysts

Adem Rifat, Nathan J. Patmore, Mary F. Mahon, Andrew S. Weller

Research output: Contribution to journal › Article › peer-review

76 Citations (Scopus)

Abstract

The synthesis of rhodium phosphine complexes partnered with carborane monoanions was reported. These complexes were evaluated as alkene hydrogenation catalysts. It was demonstrated that changing the counterion within the domain of closo-monocarboranes can have a significant effect on the efficiency of hydrogenation by cationic rhodium phosphine catalysts.

Original language	English
Pages (from-to)	2856-2865
Number of pages	10
Journal	Organometallics
Volume	21
Issue number	14
Early online date	4 Jun 2002
DOIs	https://doi.org/10.1021/om020077r
Publication status	Published - 1 Jul 2002
Externally published	Yes

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title = "Rhodium phosphines partnered with the carborane monoanions [CB11H6Y6]- (Y = H, Br). Synthesis and evaluation as alkene hydrogenation catalysts",

abstract = "The synthesis of rhodium phosphine complexes partnered with carborane monoanions was reported. These complexes were evaluated as alkene hydrogenation catalysts. It was demonstrated that changing the counterion within the domain of closo-monocarboranes can have a significant effect on the efficiency of hydrogenation by cationic rhodium phosphine catalysts.",

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AU - Weller, Andrew S.

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AB - The synthesis of rhodium phosphine complexes partnered with carborane monoanions was reported. These complexes were evaluated as alkene hydrogenation catalysts. It was demonstrated that changing the counterion within the domain of closo-monocarboranes can have a significant effect on the efficiency of hydrogenation by cationic rhodium phosphine catalysts.

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Rhodium phosphines partnered with the carborane monoanions [CB₁₁H₆Y₆]^- (Y = H, Br). Synthesis and evaluation as alkene hydrogenation catalysts

Abstract

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