Rhodium phosphines partnered with the carborane monoanions [CB11H6Y6]- (Y = H, Br). Synthesis and evaluation as alkene hydrogenation catalysts

Adem Rifat, Nathan J. Patmore, Mary F. Mahon, Andrew S. Weller

Research output: Contribution to journalArticle

72 Citations (Scopus)

Abstract

The synthesis of rhodium phosphine complexes partnered with carborane monoanions was reported. These complexes were evaluated as alkene hydrogenation catalysts. It was demonstrated that changing the counterion within the domain of closo-monocarboranes can have a significant effect on the efficiency of hydrogenation by cationic rhodium phosphine catalysts.

LanguageEnglish
Pages2856-2865
Number of pages10
JournalOrganometallics
Volume21
Issue number14
Early online date4 Jun 2002
DOIs
Publication statusPublished - 1 Jul 2002
Externally publishedYes

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phosphine
Phosphines
carborane
Rhodium
Alkenes
rhodium
phosphines
alkenes
Hydrogenation
hydrogenation
catalysts
Catalysts
evaluation
synthesis

Cite this

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abstract = "The synthesis of rhodium phosphine complexes partnered with carborane monoanions was reported. These complexes were evaluated as alkene hydrogenation catalysts. It was demonstrated that changing the counterion within the domain of closo-monocarboranes can have a significant effect on the efficiency of hydrogenation by cationic rhodium phosphine catalysts.",
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Rhodium phosphines partnered with the carborane monoanions [CB11H6Y6]- (Y = H, Br). Synthesis and evaluation as alkene hydrogenation catalysts. / Rifat, Adem; Patmore, Nathan J.; Mahon, Mary F.; Weller, Andrew S.

In: Organometallics, Vol. 21, No. 14, 01.07.2002, p. 2856-2865.

Research output: Contribution to journalArticle

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