Selective guest recognition by a self-assembled paramagnetic cage complex

Simon Turega, Martina Whitehead, Benjamin R. Hall, Mairi F. Haddow, Christopher A. Hunter, Michael D. Ward

Research output: Contribution to journalArticle

56 Citations (Scopus)

Abstract

A cubic cage complex assembled from twelve bis-bidentate ligands and eight Co(ii) ions provides a cavity that selectively recognises and binds coumarin in MeCN solution. The cage portals are large enough to allow guest exchange, but small enough to provide a kinetic trap; the cage paramagnetism facilitates detailed NMR analysis.

Original languageEnglish
Pages (from-to)2752-2754
Number of pages3
JournalChemical Communications
Volume48
Issue number22
DOIs
Publication statusPublished - 14 Mar 2012
Externally publishedYes

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Paramagnetism
Ligands
Nuclear magnetic resonance
Ions
Kinetics
coumarin

Cite this

Turega, S., Whitehead, M., Hall, B. R., Haddow, M. F., Hunter, C. A., & Ward, M. D. (2012). Selective guest recognition by a self-assembled paramagnetic cage complex. Chemical Communications, 48(22), 2752-2754. https://doi.org/10.1039/c2cc17369g
Turega, Simon ; Whitehead, Martina ; Hall, Benjamin R. ; Haddow, Mairi F. ; Hunter, Christopher A. ; Ward, Michael D. / Selective guest recognition by a self-assembled paramagnetic cage complex. In: Chemical Communications. 2012 ; Vol. 48, No. 22. pp. 2752-2754.
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Turega, S, Whitehead, M, Hall, BR, Haddow, MF, Hunter, CA & Ward, MD 2012, 'Selective guest recognition by a self-assembled paramagnetic cage complex', Chemical Communications, vol. 48, no. 22, pp. 2752-2754. https://doi.org/10.1039/c2cc17369g

Selective guest recognition by a self-assembled paramagnetic cage complex. / Turega, Simon; Whitehead, Martina; Hall, Benjamin R.; Haddow, Mairi F.; Hunter, Christopher A.; Ward, Michael D.

In: Chemical Communications, Vol. 48, No. 22, 14.03.2012, p. 2752-2754.

Research output: Contribution to journalArticle

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