Abstract
A cubic cage complex assembled from twelve bis-bidentate ligands and eight Co(ii) ions provides a cavity that selectively recognises and binds coumarin in MeCN solution. The cage portals are large enough to allow guest exchange, but small enough to provide a kinetic trap; the cage paramagnetism facilitates detailed NMR analysis.
| Original language | English |
|---|---|
| Pages (from-to) | 2752-2754 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 48 |
| Issue number | 22 |
| DOIs | |
| Publication status | Published - 14 Mar 2012 |
| Externally published | Yes |
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Selective guest recognition by a self-assembled paramagnetic cage complex. / Turega, Simon; Whitehead, Martina; Hall, Benjamin R.; Haddow, Mairi F.; Hunter, Christopher A.; Ward, Michael D.
In: Chemical Communications, Vol. 48, No. 22, 14.03.2012, p. 2752-2754.Research output: Contribution to journal › Article
TY - JOUR
T1 - Selective guest recognition by a self-assembled paramagnetic cage complex
AU - Turega, Simon
AU - Whitehead, Martina
AU - Hall, Benjamin R.
AU - Haddow, Mairi F.
AU - Hunter, Christopher A.
AU - Ward, Michael D.
PY - 2012/3/14
Y1 - 2012/3/14
N2 - A cubic cage complex assembled from twelve bis-bidentate ligands and eight Co(ii) ions provides a cavity that selectively recognises and binds coumarin in MeCN solution. The cage portals are large enough to allow guest exchange, but small enough to provide a kinetic trap; the cage paramagnetism facilitates detailed NMR analysis.
AB - A cubic cage complex assembled from twelve bis-bidentate ligands and eight Co(ii) ions provides a cavity that selectively recognises and binds coumarin in MeCN solution. The cage portals are large enough to allow guest exchange, but small enough to provide a kinetic trap; the cage paramagnetism facilitates detailed NMR analysis.
UR - http://www.scopus.com/inward/record.url?scp=84857217134&partnerID=8YFLogxK
U2 - 10.1039/c2cc17369g
DO - 10.1039/c2cc17369g
M3 - Article
VL - 48
SP - 2752
EP - 2754
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 22
ER -