Selective guest recognition by a self-assembled paramagnetic cage complex

Simon Turega; Martina Whitehead; Benjamin R. Hall; Mairi F. Haddow; Christopher A. Hunter; Michael D. Ward

doi:10.1039/c2cc17369g

Selective guest recognition by a self-assembled paramagnetic cage complex

Simon Turega, Martina Whitehead, Benjamin R. Hall, Mairi F. Haddow, Christopher A. Hunter, Michael D. Ward

Research output: Contribution to journal › Article › peer-review

63 Citations (Scopus)

Abstract

A cubic cage complex assembled from twelve bis-bidentate ligands and eight Co(ii) ions provides a cavity that selectively recognises and binds coumarin in MeCN solution. The cage portals are large enough to allow guest exchange, but small enough to provide a kinetic trap; the cage paramagnetism facilitates detailed NMR analysis.

Original language	English
Pages (from-to)	2752-2754
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	22
DOIs	https://doi.org/10.1039/c2cc17369g
Publication status	Published - 14 Mar 2012
Externally published	Yes

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title = "Selective guest recognition by a self-assembled paramagnetic cage complex",

abstract = "A cubic cage complex assembled from twelve bis-bidentate ligands and eight Co(ii) ions provides a cavity that selectively recognises and binds coumarin in MeCN solution. The cage portals are large enough to allow guest exchange, but small enough to provide a kinetic trap; the cage paramagnetism facilitates detailed NMR analysis.",

author = "Simon Turega and Martina Whitehead and Hall, {Benjamin R.} and Haddow, {Mairi F.} and Hunter, {Christopher A.} and Ward, {Michael D.}",

year = "2012",

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doi = "10.1039/c2cc17369g",

language = "English",

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T1 - Selective guest recognition by a self-assembled paramagnetic cage complex

AU - Turega, Simon

AU - Whitehead, Martina

AU - Hall, Benjamin R.

AU - Haddow, Mairi F.

AU - Hunter, Christopher A.

AU - Ward, Michael D.

PY - 2012/3/14

Y1 - 2012/3/14

N2 - A cubic cage complex assembled from twelve bis-bidentate ligands and eight Co(ii) ions provides a cavity that selectively recognises and binds coumarin in MeCN solution. The cage portals are large enough to allow guest exchange, but small enough to provide a kinetic trap; the cage paramagnetism facilitates detailed NMR analysis.

AB - A cubic cage complex assembled from twelve bis-bidentate ligands and eight Co(ii) ions provides a cavity that selectively recognises and binds coumarin in MeCN solution. The cage portals are large enough to allow guest exchange, but small enough to provide a kinetic trap; the cage paramagnetism facilitates detailed NMR analysis.

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U2 - 10.1039/c2cc17369g

DO - 10.1039/c2cc17369g

M3 - Article

AN - SCOPUS:84857217134

SN - 1359-7345

VL - 48

SP - 2752

EP - 2754

JO - Chemical Communications

JF - Chemical Communications

IS - 22

ER -

Selective guest recognition by a self-assembled paramagnetic cage complex

Abstract

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