Self-Assembled Anion-Binding Cryptand for the Selective Liquid–Liquid Extraction of Phosphate Anions

Rebecca Andrews, Sabera Begum, Christopher J. Clemett, Robert A. Faulkner, Michael L. Ginger, Jane Harmer, Marco Molinari, Gareth M.B. Parkes, Zuhlqurnain M.H. Qureshi, Craig R. Rice, Michael D. Ward, Howard M. Williams, Philippe B. Wilson

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

The ligands L1 and L2 form trinuclear self-assembled complexes with Cu2+ (i.e. [(L1)2Cu3]6+ or [(L2)2Cu3]6+) both of which act as a host to a variety of anions. Inclusion of long aliphatic chains on these ligands allows the assemblies to extract anions from aqueous media into organic solvents. Phosphate can be removed from water efficiently and highly selectively, even in the presence of other anions.

Original languageEnglish
Pages (from-to)20480-20484
Number of pages5
JournalAngewandte Chemie - International Edition
Volume59
Issue number46
Early online date2 Aug 2020
DOIs
Publication statusPublished - 9 Nov 2020

Fingerprint

Dive into the research topics of 'Self-Assembled Anion-Binding Cryptand for the Selective Liquid–Liquid Extraction of Phosphate Anions'. Together they form a unique fingerprint.

Cite this