Self-assembly of a 3-D triply interlocked chiral [2]catenane

A. Westcott; J. Fisher; L.P. Harding; P. Rizkallah; M.J. Hardie

doi:10.1021/ja8002149

Self-assembly of a 3-D triply interlocked chiral [2]catenane

A. Westcott, J. Fisher, L.P. Harding, P. Rizkallah, M.J. Hardie

Research output: Contribution to journal › Article › peer-review

179 Citations (Scopus)

Abstract

A tripodal cyclotriveratrylene-based ligand with chelating 2,2‘-bipyridine arms self-assembles with either Zn(NO3)2 or Co(NO3)2 to give 3-D trigonal bipyramidal [M3L2] cage assemblies. These cages triply interlock forming [2]catenane species that have been characterized by mass spectrometry and, in the case of the Zn(II) complex, by X-ray crystallography.

Original language	English
Pages (from-to)	2950-2951
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	130
Issue number	10
DOIs	https://doi.org/10.1021/ja8002149
Publication status	Published - Feb 2008

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abstract = "A tripodal cyclotriveratrylene-based ligand with chelating 2,2{\textquoteleft}-bipyridine arms self-assembles with either Zn(NO3)2 or Co(NO3)2 to give 3-D trigonal bipyramidal [M3L2] cage assemblies. These cages triply interlock forming [2]catenane species that have been characterized by mass spectrometry and, in the case of the Zn(II) complex, by X-ray crystallography.",

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AU - Rizkallah, P.

AU - Hardie, M.J.

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Self-assembly of a 3-D triply interlocked chiral [2]catenane

Abstract

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