Self-assembly of a molecular M8L12cube having S6symmetry

Z.R. Bell; L.P. Harding; M.D. Ward

doi:10.1039/B307172N

Self-assembly of a molecular M8L12cube having S6symmetry

Z.R. Bell, L.P. Harding, M.D. Ward

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80 Citations (Scopus)

Abstract

Reaction of the bis-bidentate ligand L1, having two bidentate pyrazolyl-pyridine termini, with Co(II) or Zn(II) results in formation of the complexes [M8(L1)12]X16 (X = perchlorate or tetrafluoroborate); [Zn8(L1)12](ClO4)16 has been structurally characterised and is a cube with a metal ion at each corner, a bridging ligand along each edge, and an anion in the central cavity.

Original language	English
Pages (from-to)	2432-2433
Number of pages	2
Journal	Chemical Communications
Volume	9
Issue number	19
DOIs	https://doi.org/10.1039/B307172N
Publication status	Published - 4 Sept 2003

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abstract = "Reaction of the bis-bidentate ligand L1, having two bidentate pyrazolyl-pyridine termini, with Co(II) or Zn(II) results in formation of the complexes [M8(L1)12]X16 (X = perchlorate or tetrafluoroborate); [Zn8(L1)12](ClO4)16 has been structurally characterised and is a cube with a metal ion at each corner, a bridging ligand along each edge, and an anion in the central cavity.",

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AU - Bell, Z.R.

AU - Harding, L.P.

AU - Ward, M.D.

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PY - 2003/9/4

Y1 - 2003/9/4

N2 - Reaction of the bis-bidentate ligand L1, having two bidentate pyrazolyl-pyridine termini, with Co(II) or Zn(II) results in formation of the complexes [M8(L1)12]X16 (X = perchlorate or tetrafluoroborate); [Zn8(L1)12](ClO4)16 has been structurally characterised and is a cube with a metal ion at each corner, a bridging ligand along each edge, and an anion in the central cavity.

AB - Reaction of the bis-bidentate ligand L1, having two bidentate pyrazolyl-pyridine termini, with Co(II) or Zn(II) results in formation of the complexes [M8(L1)12]X16 (X = perchlorate or tetrafluoroborate); [Zn8(L1)12](ClO4)16 has been structurally characterised and is a cube with a metal ion at each corner, a bridging ligand along each edge, and an anion in the central cavity.

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JO - Chemical Communications

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Self-assembly of a molecular M8L12cube having S6symmetry

Abstract

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