Star-burst prisms with cyclotriveratrylene-type ligands

A [Pd6L8]12+stella octangular structure

T.K. Ronson, J. Fisher, L.P. Harding, M.J. Hardie

Research output: Contribution to journalArticle

100 Citations (Scopus)

Abstract

Star treatment: Host molecule tris(isonicotinoyl)cyclotriguaiacylene self‐assembles with Pd(NO3)2 to form a [Pd6L8]12+ metallo‐supramolecular cage of over 3 nm in diameter that resembles a stella octangular structure (see picture). ESMS and DOSY NMR studies show the assembly also exists in solution with a hydrodynamic radius of approximately 19 Å.
Original languageEnglish
Pages (from-to)9086-9088
Number of pages3
JournalAngewandte Chemie - International Edition
Volume46
Issue number47
DOIs
Publication statusPublished - Dec 2007

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Prisms
Stars
Hydrodynamics
Ligands
Nuclear magnetic resonance
Molecules
cyclotriveratrylene

Cite this

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abstract = "Star treatment: Host molecule tris(isonicotinoyl)cyclotriguaiacylene self‐assembles with Pd(NO3)2 to form a [Pd6L8]12+ metallo‐supramolecular cage of over 3 nm in diameter that resembles a stella octangular structure (see picture). ESMS and DOSY NMR studies show the assembly also exists in solution with a hydrodynamic radius of approximately 19 {\AA}.",
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Star-burst prisms with cyclotriveratrylene-type ligands : A [Pd6L8]12+stella octangular structure. / Ronson, T.K.; Fisher, J.; Harding, L.P.; Hardie, M.J.

In: Angewandte Chemie - International Edition, Vol. 46, No. 47, 12.2007, p. 9086-9088.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Star-burst prisms with cyclotriveratrylene-type ligands

T2 - A [Pd6L8]12+stella octangular structure

AU - Ronson, T.K.

AU - Fisher, J.

AU - Harding, L.P.

AU - Hardie, M.J.

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AB - Star treatment: Host molecule tris(isonicotinoyl)cyclotriguaiacylene self‐assembles with Pd(NO3)2 to form a [Pd6L8]12+ metallo‐supramolecular cage of over 3 nm in diameter that resembles a stella octangular structure (see picture). ESMS and DOSY NMR studies show the assembly also exists in solution with a hydrodynamic radius of approximately 19 Å.

U2 - 10.1002/anie.200703903

DO - 10.1002/anie.200703903

M3 - Article

VL - 46

SP - 9086

EP - 9088

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

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