Star-burst prisms with cyclotriveratrylene-type ligands: A [Pd6L8]12+stella octangular structure

T.K. Ronson, J. Fisher, L.P. Harding, M.J. Hardie

Research output: Contribution to journalArticle

103 Citations (Scopus)

Abstract

Star treatment: Host molecule tris(isonicotinoyl)cyclotriguaiacylene self‐assembles with Pd(NO3)2 to form a [Pd6L8]12+ metallo‐supramolecular cage of over 3 nm in diameter that resembles a stella octangular structure (see picture). ESMS and DOSY NMR studies show the assembly also exists in solution with a hydrodynamic radius of approximately 19 Å.
Original languageEnglish
Pages (from-to)9086-9088
Number of pages3
JournalAngewandte Chemie - International Edition
Volume46
Issue number47
DOIs
Publication statusPublished - Dec 2007

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