Study of the thermal behavior in oxidative and pyrolysis conditions of some transition metals complexes with Lornoxicam as ligand using the techniques

TG-DSC, DSC, HSM and EGA (TG-FTIR and HSM-MS)

Geórgia A.C. Zangaro, Ana C.S. Carvalho, Bruno Ekawa, André L.C.S. do Nascimento, Wilhan D.G. Nunes, Richard P. Fernandes, Gareth M.B. Parkes, Gage P. Ashton, Massao Ionashiro, Flávio J. Caires

Research output: Contribution to journalArticle

Abstract

Lornoxicam metal complexes [M(Lor)2(OH2)2]∙nH2O, where M represents the bivalent transition metals (Mn(II) to Zn(II)), Lor is Lornoxicam ligand and n = 2.0 or 2.5 were synthesized. The compounds were characterized by elemental analysis (EA), powder X-ray diffraction (PXRD), infrared spectroscopy (FTIR), simultaneous thermogravimetry and differential scanning calorimetry (TG-DSC) under oxidizing and pyrolysis conditions, differential scanning calorimetry (DSC), hot-stage microscopy (HSM) and evolved gas analysis (EGA) by coupled hot-stage microscopy (HSM-MS) and Fourier transform infrared (TG–FTIR). Regardless of the atmosphere, the thermal stability and thermal behavior up to the first two mass loss steps of the anhydrous compound were similar, only differing significantly in the last steps. The main gaseous products released were H2O (dehydration), SO2, CO, CO2, COS, HCN, HNCO, Methyl Isocyanate, and Ethyl Isocyanate. In addition, FTIR data suggest that pyridyl and carboxyl groups are the coordination sites for metal ions and confirm the presence of differing bounded waters.

Original languageEnglish
Article number178399
Number of pages10
JournalThermochimica Acta
Volume681
Early online date3 Sep 2019
DOIs
Publication statusPublished - 1 Nov 2019

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Gas fuel analysis
gas analysis
Coordination Complexes
Metal complexes
thermogravimetry
Transition metals
pyrolysis
Thermogravimetric analysis
Differential scanning calorimetry
Microscopic examination
isocyanates
Pyrolysis
heat measurement
transition metals
Ligands
microscopy
ligands
scanning
carboxyl group
Carbon Monoxide

Cite this

Zangaro, Geórgia A.C. ; Carvalho, Ana C.S. ; Ekawa, Bruno ; do Nascimento, André L.C.S. ; Nunes, Wilhan D.G. ; Fernandes, Richard P. ; Parkes, Gareth M.B. ; Ashton, Gage P. ; Ionashiro, Massao ; Caires, Flávio J. / Study of the thermal behavior in oxidative and pyrolysis conditions of some transition metals complexes with Lornoxicam as ligand using the techniques : TG-DSC, DSC, HSM and EGA (TG-FTIR and HSM-MS). In: Thermochimica Acta. 2019 ; Vol. 681.
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abstract = "Lornoxicam metal complexes [M(Lor)2(OH2)2]∙nH2O, where M represents the bivalent transition metals (Mn(II) to Zn(II)), Lor is Lornoxicam ligand and n = 2.0 or 2.5 were synthesized. The compounds were characterized by elemental analysis (EA), powder X-ray diffraction (PXRD), infrared spectroscopy (FTIR), simultaneous thermogravimetry and differential scanning calorimetry (TG-DSC) under oxidizing and pyrolysis conditions, differential scanning calorimetry (DSC), hot-stage microscopy (HSM) and evolved gas analysis (EGA) by coupled hot-stage microscopy (HSM-MS) and Fourier transform infrared (TG–FTIR). Regardless of the atmosphere, the thermal stability and thermal behavior up to the first two mass loss steps of the anhydrous compound were similar, only differing significantly in the last steps. The main gaseous products released were H2O (dehydration), SO2, CO, CO2, COS, HCN, HNCO, Methyl Isocyanate, and Ethyl Isocyanate. In addition, FTIR data suggest that pyridyl and carboxyl groups are the coordination sites for metal ions and confirm the presence of differing bounded waters.",
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Study of the thermal behavior in oxidative and pyrolysis conditions of some transition metals complexes with Lornoxicam as ligand using the techniques : TG-DSC, DSC, HSM and EGA (TG-FTIR and HSM-MS). / Zangaro, Geórgia A.C.; Carvalho, Ana C.S.; Ekawa, Bruno; do Nascimento, André L.C.S.; Nunes, Wilhan D.G.; Fernandes, Richard P.; Parkes, Gareth M.B.; Ashton, Gage P.; Ionashiro, Massao; Caires, Flávio J.

In: Thermochimica Acta, Vol. 681, 178399, 01.11.2019.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Study of the thermal behavior in oxidative and pyrolysis conditions of some transition metals complexes with Lornoxicam as ligand using the techniques

T2 - TG-DSC, DSC, HSM and EGA (TG-FTIR and HSM-MS)

AU - Zangaro, Geórgia A.C.

AU - Carvalho, Ana C.S.

AU - Ekawa, Bruno

AU - do Nascimento, André L.C.S.

AU - Nunes, Wilhan D.G.

AU - Fernandes, Richard P.

AU - Parkes, Gareth M.B.

AU - Ashton, Gage P.

AU - Ionashiro, Massao

AU - Caires, Flávio J.

PY - 2019/11/1

Y1 - 2019/11/1

N2 - Lornoxicam metal complexes [M(Lor)2(OH2)2]∙nH2O, where M represents the bivalent transition metals (Mn(II) to Zn(II)), Lor is Lornoxicam ligand and n = 2.0 or 2.5 were synthesized. The compounds were characterized by elemental analysis (EA), powder X-ray diffraction (PXRD), infrared spectroscopy (FTIR), simultaneous thermogravimetry and differential scanning calorimetry (TG-DSC) under oxidizing and pyrolysis conditions, differential scanning calorimetry (DSC), hot-stage microscopy (HSM) and evolved gas analysis (EGA) by coupled hot-stage microscopy (HSM-MS) and Fourier transform infrared (TG–FTIR). Regardless of the atmosphere, the thermal stability and thermal behavior up to the first two mass loss steps of the anhydrous compound were similar, only differing significantly in the last steps. The main gaseous products released were H2O (dehydration), SO2, CO, CO2, COS, HCN, HNCO, Methyl Isocyanate, and Ethyl Isocyanate. In addition, FTIR data suggest that pyridyl and carboxyl groups are the coordination sites for metal ions and confirm the presence of differing bounded waters.

AB - Lornoxicam metal complexes [M(Lor)2(OH2)2]∙nH2O, where M represents the bivalent transition metals (Mn(II) to Zn(II)), Lor is Lornoxicam ligand and n = 2.0 or 2.5 were synthesized. The compounds were characterized by elemental analysis (EA), powder X-ray diffraction (PXRD), infrared spectroscopy (FTIR), simultaneous thermogravimetry and differential scanning calorimetry (TG-DSC) under oxidizing and pyrolysis conditions, differential scanning calorimetry (DSC), hot-stage microscopy (HSM) and evolved gas analysis (EGA) by coupled hot-stage microscopy (HSM-MS) and Fourier transform infrared (TG–FTIR). Regardless of the atmosphere, the thermal stability and thermal behavior up to the first two mass loss steps of the anhydrous compound were similar, only differing significantly in the last steps. The main gaseous products released were H2O (dehydration), SO2, CO, CO2, COS, HCN, HNCO, Methyl Isocyanate, and Ethyl Isocyanate. In addition, FTIR data suggest that pyridyl and carboxyl groups are the coordination sites for metal ions and confirm the presence of differing bounded waters.

KW - HSM-MS

KW - Lornoxicam

KW - TG-FTIR

KW - Thermal Analysis

KW - Transition metal complexes

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U2 - 10.1016/j.tca.2019.178399

DO - 10.1016/j.tca.2019.178399

M3 - Article

VL - 681

JO - Thermochimica Acta

JF - Thermochimica Acta

SN - 0040-6031

M1 - 178399

ER -