Abstract
The synthesis of {Mo(η-L)(CO)3}+ (η-L = C5H5 or C5Me5) fragments, ligated to the mono-anionic, weakly co-ordinating, carboranes [closo-l-CB11H12]- and [closo-CB11Br6H6]-, has been investigated. Treatment of [MoCp(CO)3X] (X = Cl or I) with Ag[CB11H12] eventually affords the zwitterionic complex [MoCp(CO)3(x-μ-H-1-CB11H12)] (x = 12 or 7), via an intermediate dimeric species [MoCp(CO)3X·Ag(CB11H12)]2 . For X = I this intermediate has been characterised by 1H, 11B NMR spectroscopy and X-ray crystallography and represents the first structurally characterised intermediate in a silver salt metathesis reaction. When the less nucleophilic carborane [CB11Br6H6]- (as its silver salt) is used metathesis is halted at the intermediate stage, affording the complex [MoCp(CO)3I·Ag(CB11Br6H6 )]2. Silver salt metathesis does not proceed using the sterically more demanding [Mo(Cp*)(CO)3I], with only intractable products isolated. The carborane anion can be introduced into the co-ordination sphere of this complex by reaction of [H(OEt2)x[CB11H12] with [Mo(Cp*)(CO)3Me] affording [Mo(Cp*)(CO)3(x-μ-H-1-CB11H12) ] (x = 12 or 7). All new compounds have been characterised by multinuclear NMR spectroscopy and X-ray crystallography.
Original language | English |
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Pages (from-to) | 277-283 |
Number of pages | 7 |
Journal | Journal of the Chemical Society, Dalton Transactions |
Issue number | 3 |
Early online date | 11 Jan 2001 |
DOIs | |
Publication status | Published - 12 Jan 2001 |
Externally published | Yes |