Synthesis and Characterization of Co-polymers Based on Methyl Methacrylate and 2-Hexyl Acrylate Containing Naphthopyrans for a Light-Sensitive Contact Lens

Cláudia R.J.O.D. Nabais, B. Mark Heron, Hermínio C. De Sousa, Maria H. Gil, Abílio J.F.N. Sobral

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Three different naphthopyrans were incorporated in co-polymers of methyl methacrylate (MMA) and 2-ethylhexyl acrylate (EHA), with and without cross-linking with ethyleneglycol dimethacrylate (EGDMA), by a free radical polymerization method. The obtained materials were characterised in terms of some of their chemical and physical properties that could be important for the final functional properties of the envisaged application. Despite other important functional properties that should be evaluated in the near future, the system based in the physical entrapment of 3,3-bis(4-methoxyphenyl)-3H-naphtho [2,1-b]pyran presented a good potential for its application as novel light-sensitive contact lenses.

Original languageEnglish
Pages (from-to)139-152
Number of pages14
JournalJournal of Biomaterials Science, Polymer Edition
Volume22
Issue number1-3
DOIs
Publication statusPublished - 1 Jan 2011
Externally publishedYes

Fingerprint

Contact lenses
Methacrylates
Contact Lenses
Polymerization
Free Radicals
Polymers
Light
Free radical polymerization
Chemical properties
Physical properties
hexyl acrylate
naphtho(2,1-b)pyran
ethylene dimethacrylate
2-ethylhexyl acrylate

Cite this

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title = "Synthesis and Characterization of Co-polymers Based on Methyl Methacrylate and 2-Hexyl Acrylate Containing Naphthopyrans for a Light-Sensitive Contact Lens",
abstract = "Three different naphthopyrans were incorporated in co-polymers of methyl methacrylate (MMA) and 2-ethylhexyl acrylate (EHA), with and without cross-linking with ethyleneglycol dimethacrylate (EGDMA), by a free radical polymerization method. The obtained materials were characterised in terms of some of their chemical and physical properties that could be important for the final functional properties of the envisaged application. Despite other important functional properties that should be evaluated in the near future, the system based in the physical entrapment of 3,3-bis(4-methoxyphenyl)-3H-naphtho [2,1-b]pyran presented a good potential for its application as novel light-sensitive contact lenses.",
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Synthesis and Characterization of Co-polymers Based on Methyl Methacrylate and 2-Hexyl Acrylate Containing Naphthopyrans for a Light-Sensitive Contact Lens. / Nabais, Cláudia R.J.O.D.; Heron, B. Mark; De Sousa, Hermínio C.; Gil, Maria H.; Sobral, Abílio J.F.N.

In: Journal of Biomaterials Science, Polymer Edition, Vol. 22, No. 1-3, 01.01.2011, p. 139-152.

Research output: Contribution to journalArticle

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AU - Nabais, Cláudia R.J.O.D.

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AU - De Sousa, Hermínio C.

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