Synthesis and Photochromism of Some Mono and Bis(Thienyl) Substituted Oxathiine 2,​2-​dioxides

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Abstract

1,2-Oxathiine 2,2-dioxides have been obtained from their respective 3,4-dihydro-4-dimethylamino precursors, for the first time, by a mild Cope elimination of the 4-dimethylamino function. The application of the 1,2-oxathiine 2,2-dioxide scaffold in materialschemistry is exemplified by the efficient P-type photochromism of the 5,6-bis(2,5-dimethyl-3-thienyl) substituted oxathiine 2,2-dioxides.
Original languageEnglish
Pages (from-to)9578-9584
Number of pages7
JournalOrganic and Biomolecular Chemistry
Volume17
Issue number44
Early online date11 Oct 2019
DOIs
Publication statusPublished - Nov 2019

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