Abstract
1,2-Oxathiine 2,2-dioxides have been obtained from their respective 3,4-dihydro-4-dimethylamino precursors, for the first time, by a mild Cope elimination of the 4-dimethylamino function. The application of the 1,2-oxathiine 2,2-dioxide scaffold in materialschemistry is exemplified by the efficient P-type photochromism of the 5,6-bis(2,5-dimethyl-3-thienyl) substituted oxathiine 2,2-dioxides.
Original language | English |
---|---|
Pages (from-to) | 9578-9584 |
Number of pages | 7 |
Journal | Organic and Biomolecular Chemistry |
Volume | 17 |
Issue number | 44 |
Early online date | 11 Oct 2019 |
DOIs | |
Publication status | Published - Nov 2019 |
Fingerprint
Dive into the research topics of 'Synthesis and Photochromism of Some Mono and Bis(Thienyl) Substituted Oxathiine 2,2-dioxides'. Together they form a unique fingerprint.Profiles
-
Stuart Aiken
- Department of Chemical Sciences - Senior Research Fellow
- School of Applied Sciences
- Centre for Functional Materials - Member
Person: Academic