TY - JOUR
T1 - Synthesis and Photochromism of Some Mono and Bis(Thienyl) Substituted Oxathiine 2,2-dioxides
AU - Aiken, Stuart
AU - Gabbutt, Christopher
AU - Heron, Bernard
AU - Rice, Craig
AU - Zonidis, Dimitrios
PY - 2019/11
Y1 - 2019/11
N2 - 1,2-Oxathiine 2,2-dioxides have been obtained from their respective 3,4-dihydro-4-dimethylamino precursors, for the first time, by a mild Cope elimination of the 4-dimethylamino function. The application of the 1,2-oxathiine 2,2-dioxide scaffold in materialschemistry is exemplified by the efficient P-type photochromism of the 5,6-bis(2,5-dimethyl-3-thienyl) substituted oxathiine 2,2-dioxides.
AB - 1,2-Oxathiine 2,2-dioxides have been obtained from their respective 3,4-dihydro-4-dimethylamino precursors, for the first time, by a mild Cope elimination of the 4-dimethylamino function. The application of the 1,2-oxathiine 2,2-dioxide scaffold in materialschemistry is exemplified by the efficient P-type photochromism of the 5,6-bis(2,5-dimethyl-3-thienyl) substituted oxathiine 2,2-dioxides.
UR - http://www.scopus.com/inward/record.url?scp=85074964388&partnerID=8YFLogxK
U2 - 10.1039/C9OB02128K
DO - 10.1039/C9OB02128K
M3 - Article
VL - 17
SP - 9578
EP - 9584
JO - Organic and Biomolecular Chemistry
JF - Organic and Biomolecular Chemistry
SN - 1477-0520
IS - 44
ER -