Synthesis and X-ray structures of cadmium-containing dinuclear double helicates derived from ligands containing N-oxide units

Georgios Bokolinis, T. Riis-Johannessen, John C. Jeffery, Craig R. Rice

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The syntheses of two novel polydentate pyridyl-thiazolyl ligands which contain an N-oxide unit on the central pyridyl ring are reported. Reaction of either of these ligands with Cd(ClO4)2·6H 2O results in the formation of a dinuclear double helicate. The solid state structures of these transition metal helicates demonstrate the ability of the N-oxide unit to partition the ligands into two separate binding domains.

Original languageEnglish
Pages (from-to)115-119
Number of pages5
JournalNew Journal of Chemistry
Volume32
Issue number1
Early online date7 Sep 2007
DOIs
Publication statusPublished - Jan 2008

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