Synthesis and X-ray structures of cadmium-containing dinuclear double helicates derived from ligands containing N-oxide units

Georgios Bokolinis, T. Riis-Johannessen, John C. Jeffery, Craig R. Rice

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The syntheses of two novel polydentate pyridyl-thiazolyl ligands which contain an N-oxide unit on the central pyridyl ring are reported. Reaction of either of these ligands with Cd(ClO4)2·6H 2O results in the formation of a dinuclear double helicate. The solid state structures of these transition metal helicates demonstrate the ability of the N-oxide unit to partition the ligands into two separate binding domains.

Original languageEnglish
Pages (from-to)115-119
Number of pages5
JournalNew Journal of Chemistry
Volume32
Issue number1
Early online date7 Sep 2007
DOIs
Publication statusPublished - Jan 2008

Fingerprint

Cadmium
Oxides
Ligands
X rays
Transition metals

Cite this

@article{2ab5c691d94f4d14a184d984c13f5e76,
title = "Synthesis and X-ray structures of cadmium-containing dinuclear double helicates derived from ligands containing N-oxide units",
abstract = "The syntheses of two novel polydentate pyridyl-thiazolyl ligands which contain an N-oxide unit on the central pyridyl ring are reported. Reaction of either of these ligands with Cd(ClO4)2·6H 2O results in the formation of a dinuclear double helicate. The solid state structures of these transition metal helicates demonstrate the ability of the N-oxide unit to partition the ligands into two separate binding domains.",
author = "Georgios Bokolinis and T. Riis-Johannessen and Jeffery, {John C.} and Rice, {Craig R.}",
year = "2008",
month = "1",
doi = "10.1039/b711039a",
language = "English",
volume = "32",
pages = "115--119",
journal = "New Journal of Chemistry",
issn = "1144-0546",
publisher = "Royal Society of Chemistry",
number = "1",

}

Synthesis and X-ray structures of cadmium-containing dinuclear double helicates derived from ligands containing N-oxide units. / Bokolinis, Georgios; Riis-Johannessen, T.; Jeffery, John C.; Rice, Craig R.

In: New Journal of Chemistry, Vol. 32, No. 1, 01.2008, p. 115-119.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Synthesis and X-ray structures of cadmium-containing dinuclear double helicates derived from ligands containing N-oxide units

AU - Bokolinis, Georgios

AU - Riis-Johannessen, T.

AU - Jeffery, John C.

AU - Rice, Craig R.

PY - 2008/1

Y1 - 2008/1

N2 - The syntheses of two novel polydentate pyridyl-thiazolyl ligands which contain an N-oxide unit on the central pyridyl ring are reported. Reaction of either of these ligands with Cd(ClO4)2·6H 2O results in the formation of a dinuclear double helicate. The solid state structures of these transition metal helicates demonstrate the ability of the N-oxide unit to partition the ligands into two separate binding domains.

AB - The syntheses of two novel polydentate pyridyl-thiazolyl ligands which contain an N-oxide unit on the central pyridyl ring are reported. Reaction of either of these ligands with Cd(ClO4)2·6H 2O results in the formation of a dinuclear double helicate. The solid state structures of these transition metal helicates demonstrate the ability of the N-oxide unit to partition the ligands into two separate binding domains.

UR - http://www.scopus.com/inward/record.url?scp=37849011224&partnerID=8YFLogxK

U2 - 10.1039/b711039a

DO - 10.1039/b711039a

M3 - Article

VL - 32

SP - 115

EP - 119

JO - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

IS - 1

ER -