Synthesis, characterisation, and reactivity of novel pseudocyclic hypervalent iodine reagents with heteroaryl carbonyl substituents

Jihan Qurban, Mohamed Elsherbini, Haifa Alharbi, Thomas Wirth

Research output: Contribution to journalArticle

Abstract

Two new hypervalent iodine reagents containing furan and thiophene moieties in addition to a carbonyl group in the vicinity of the iodine atom were synthesised and characterised. The X-ray analysis of both compounds revealed a strong intramolecular contact between the carbonyl oxygen and the hypervalent iodine atom with tosylate as a counter ion. The two reagents showed a broad range of synthetic applications and proved to be versatile oxidizing agents.
Original languageEnglish
Pages (from-to)7998-8000
Number of pages3
JournalChemical Communications
Issue number55
Early online date17 Jun 2019
DOIs
Publication statusPublished - 14 Jul 2019
Externally publishedYes

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Iodine
Thiophenes
Atoms
Radiation counters
X ray analysis
Thiophene
Oxidants
Oxygen

Cite this

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Synthesis, characterisation, and reactivity of novel pseudocyclic hypervalent iodine reagents with heteroaryl carbonyl substituents. / Qurban, Jihan ; Elsherbini, Mohamed; Alharbi, Haifa; Wirth, Thomas.

In: Chemical Communications, No. 55, 14.07.2019, p. 7998-8000.

Research output: Contribution to journalArticle

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