Synthesis, characterisation, and reactivity of novel pseudocyclic hypervalent iodine reagents with heteroaryl carbonyl substituents

Jihan  Qurban; Mohamed Elsherbini; Haifa Alharbi; Thomas Wirth

doi:10.1039/C9CC03905H

Synthesis, characterisation, and reactivity of novel pseudocyclic hypervalent iodine reagents with heteroaryl carbonyl substituents

Jihan Qurban, Mohamed Elsherbini, Haifa Alharbi, Thomas Wirth

Cardiff University

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Two new hypervalent iodine reagents containing furan and thiophene moieties in addition to a carbonyl group in the vicinity of the iodine atom were synthesised and characterised. The X-ray analysis of both compounds revealed a strong intramolecular contact between the carbonyl oxygen and the hypervalent iodine atom with tosylate as a counter ion. The two reagents showed a broad range of synthetic applications and proved to be versatile oxidizing agents.

Original language	English
Pages (from-to)	7998-8000
Number of pages	3
Journal	Chemical Communications
Issue number	55
Early online date	17 Jun 2019
DOIs	https://doi.org/10.1039/C9CC03905H
Publication status	Published - 14 Jul 2019
Externally published	Yes

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Synthesis, characterisation, and reactivity of novel pseudocyclic hypervalent iodine reagents with heteroaryl carbonyl substituents

Abstract

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