Synthesis of densely functionalised arenes using [2 + 2 + 2] cycloaddition reactions

Jonathan Clayden; Wesley J. Moran

doi:10.1039/b700353f

Synthesis of densely functionalised arenes using [2 + 2 + 2] cycloaddition reactions

Jonathan Clayden, Wesley J. Moran

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

Rh(I)-catalysed [2 + 2 + 2] cycloaddition allows the synthesis of aryl ethers and diaryl methanes containing a high degree of steric hindrance from relatively simple diyne and alkyne precursors. The diarylmethanes made in this way show no evidence in their NMR spectra, however, of rotational restriction.

Original language	English
Pages (from-to)	1028-1030
Number of pages	3
Journal	Organic and Biomolecular Chemistry
Volume	5
Issue number	7
Early online date	27 Feb 2007
DOIs	https://doi.org/10.1039/b700353f
Publication status	Published - 7 Apr 2007
Externally published	Yes

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abstract = "Rh(I)-catalysed [2 + 2 + 2] cycloaddition allows the synthesis of aryl ethers and diaryl methanes containing a high degree of steric hindrance from relatively simple diyne and alkyne precursors. The diarylmethanes made in this way show no evidence in their NMR spectra, however, of rotational restriction.",

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Synthesis of densely functionalised arenes using [2 + 2 + 2] cycloaddition reactions

Abstract

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