The directed lithiation of some 3-acylchromone acetals

G. Elena Daia; Christopher D. Gabbutt; John D. Hepworth; B. Mark Heron; David E. Hibbs; Michael B. Hursthouse

doi:10.1016/S0040-4039(97)10733-X

The directed lithiation of some 3-acylchromone acetals

G. Elena Daia, Christopher D. Gabbutt, John D. Hepworth, B. Mark Heron, David E. Hibbs, Michael B. Hursthouse

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

3-Acylchromone acetals are lithiated at C-2. Subsequent electrophilic trapping gives chromones 4 together with a ring-contracted dimer 6. During the formation of some acetals, an acid-catalysed rearrangement to a 2-substituted 3-formylchromone acetal is observed.

Original language	English
Pages (from-to)	1215-1218
Number of pages	4
Journal	Tetrahedron Letters
Volume	39
Issue number	10
DOIs	https://doi.org/10.1016/S0040-4039(97)10733-X
Publication status	Published - 5 Mar 1998
Externally published	Yes

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title = "The directed lithiation of some 3-acylchromone acetals",

abstract = "3-Acylchromone acetals are lithiated at C-2. Subsequent electrophilic trapping gives chromones 4 together with a ring-contracted dimer 6. During the formation of some acetals, an acid-catalysed rearrangement to a 2-substituted 3-formylchromone acetal is observed.",

author = "Daia, {G. Elena} and Gabbutt, {Christopher D.} and Hepworth, {John D.} and Heron, {B. Mark} and Hibbs, {David E.} and Hursthouse, {Michael B.}",

year = "1998",

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doi = "10.1016/S0040-4039(97)10733-X",

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journal = "Tetrahedron Letters",

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T1 - The directed lithiation of some 3-acylchromone acetals

AU - Daia, G. Elena

AU - Gabbutt, Christopher D.

AU - Hepworth, John D.

AU - Heron, B. Mark

AU - Hibbs, David E.

AU - Hursthouse, Michael B.

PY - 1998/3/5

Y1 - 1998/3/5

N2 - 3-Acylchromone acetals are lithiated at C-2. Subsequent electrophilic trapping gives chromones 4 together with a ring-contracted dimer 6. During the formation of some acetals, an acid-catalysed rearrangement to a 2-substituted 3-formylchromone acetal is observed.

AB - 3-Acylchromone acetals are lithiated at C-2. Subsequent electrophilic trapping gives chromones 4 together with a ring-contracted dimer 6. During the formation of some acetals, an acid-catalysed rearrangement to a 2-substituted 3-formylchromone acetal is observed.

UR - http://www.scopus.com/inward/record.url?scp=0032485442&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(97)10733-X

DO - 10.1016/S0040-4039(97)10733-X

M3 - Article

AN - SCOPUS:0032485442

VL - 39

SP - 1215

EP - 1218

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 10

ER -

The directed lithiation of some 3-acylchromone acetals

Abstract

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