TY - JOUR
T1 - trans Deformation of a Carbon-Carbon Triple Bond in Response to Incipient Nucleophilic Attack
T2 - The X-Ray Crystal Structure of Ethyl 3-(2-Nitrophenyl)propynoate at 150 K
AU - Rice, Craig R.
AU - Wallis, John D.
PY - 1993
Y1 - 1993
N2 - In the title compound 1 the electron-deficient alkyne bond shows a pronounced trans distortion in response to an adjacent electron rich nitro O atom, suggesting that the more favourable reaction coordinate for addition of nucleophiles to activated alkynes involves trans rather than cis addition.
AB - In the title compound 1 the electron-deficient alkyne bond shows a pronounced trans distortion in response to an adjacent electron rich nitro O atom, suggesting that the more favourable reaction coordinate for addition of nucleophiles to activated alkynes involves trans rather than cis addition.
UR - http://www.scopus.com/inward/record.url?scp=37049083646&partnerID=8YFLogxK
U2 - 10.1039/C39930000572
DO - 10.1039/C39930000572
M3 - Article
AN - SCOPUS:37049083646
SN - 0022-4936
SP - 572
EP - 574
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 6
ER -