TY - JOUR
T1 - Tricarbonylchlorido(6′,7′-dihydro-5′H-spiro[cyclohexane- 1,6′-dipyrido[3,2-d
T2 - 2′,3′-f][1,3]diazepine] -κ2 N 1,N 11)rhenium(I)
AU - Clegg, Oliver R.
AU - Harding, Lindsay P.
AU - Miller, John W.
AU - Rice, Craig R.
PY - 2013/10/1
Y1 - 2013/10/1
N2 - In the title compound, [ReCl(C16H18N4)(CO)3], the ReI ion is coordinated in a distorted octahedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclohexane group is orientated in a transoid fashion with respect to the chloride ligand. In the crystal, N - H⋯Cl hydrogen bonds link complex molecules, forming a two-dimensional network parallel to (100).
AB - In the title compound, [ReCl(C16H18N4)(CO)3], the ReI ion is coordinated in a distorted octahedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclohexane group is orientated in a transoid fashion with respect to the chloride ligand. In the crystal, N - H⋯Cl hydrogen bonds link complex molecules, forming a two-dimensional network parallel to (100).
UR - http://www.scopus.com/inward/record.url?scp=84885096075&partnerID=8YFLogxK
U2 - 10.1107/S1600536813024288
DO - 10.1107/S1600536813024288
M3 - Article
AN - SCOPUS:84885096075
VL - 69
SP - m527
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 10
ER -