Tricarbonylchlorido(6′,7′-dihydro-5′H-spiro[cyclohexane- 1,6′-dipyrido[3,2-d

2′,3′-f][1,3]diazepine] -κ2 N 1,N 11)rhenium(I)

Oliver R. Clegg, Lindsay P. Harding, John W. Miller, Craig R. Rice

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

In the title compound, [ReCl(C16H18N4)(CO)3], the ReI ion is coordinated in a distorted octahedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclohexane group is orientated in a transoid fashion with respect to the chloride ligand. In the crystal, N - H⋯Cl hydrogen bonds link complex molecules, forming a two-dimensional network parallel to (100).

Original languageEnglish
Pages (from-to)m527
JournalActa Crystallographica Section E: Structure Reports Online
Volume69
Issue number10
DOIs
Publication statusPublished - 1 Oct 2013

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Rhenium
rhenium
Cyclohexane
cyclohexane
Ligands
Atoms
ligands
Carbon Monoxide
atoms
Chlorides
Hydrogen bonds
chlorides
Ions
hydrogen bonds
Crystals
Molecules
Geometry
geometry
crystals
molecules

Cite this

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title = "Tricarbonylchlorido(6′,7′-dihydro-5′H-spiro[cyclohexane- 1,6′-dipyrido[3,2-d: 2′,3′-f][1,3]diazepine] -κ2 N 1,N 11)rhenium(I)",
abstract = "In the title compound, [ReCl(C16H18N4)(CO)3], the ReI ion is coordinated in a distorted octahedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclohexane group is orientated in a transoid fashion with respect to the chloride ligand. In the crystal, N - H⋯Cl hydrogen bonds link complex molecules, forming a two-dimensional network parallel to (100).",
author = "Clegg, {Oliver R.} and Harding, {Lindsay P.} and Miller, {John W.} and Rice, {Craig R.}",
year = "2013",
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day = "1",
doi = "10.1107/S1600536813024288",
language = "English",
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journal = "Acta Crystallographica Section E: Structure Reports Online",
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TY - JOUR

T1 - Tricarbonylchlorido(6′,7′-dihydro-5′H-spiro[cyclohexane- 1,6′-dipyrido[3,2-d

T2 - 2′,3′-f][1,3]diazepine] -κ2 N 1,N 11)rhenium(I)

AU - Clegg, Oliver R.

AU - Harding, Lindsay P.

AU - Miller, John W.

AU - Rice, Craig R.

PY - 2013/10/1

Y1 - 2013/10/1

N2 - In the title compound, [ReCl(C16H18N4)(CO)3], the ReI ion is coordinated in a distorted octahedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclohexane group is orientated in a transoid fashion with respect to the chloride ligand. In the crystal, N - H⋯Cl hydrogen bonds link complex molecules, forming a two-dimensional network parallel to (100).

AB - In the title compound, [ReCl(C16H18N4)(CO)3], the ReI ion is coordinated in a distorted octahedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclohexane group is orientated in a transoid fashion with respect to the chloride ligand. In the crystal, N - H⋯Cl hydrogen bonds link complex molecules, forming a two-dimensional network parallel to (100).

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U2 - 10.1107/S1600536813024288

DO - 10.1107/S1600536813024288

M3 - Article

VL - 69

SP - m527

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 10

ER -