TY - JOUR
T1 - Tricarbonylchlorido(6′,7′-dihydro-5′H-spiro[cyclopentane- 1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine] -κ2 N 1,N 11)rhenium(I)
AU - Clegg, O.R.
AU - Harding, L.P.
AU - Miller, J.W.
AU - Rice, C.R.
N1 - cited By 1
PY - 2013/10
Y1 - 2013/10
N2 - In the title compound, [ReCl(C15H16N4)(CO)3], the ReI ion is coordinated in a distorted octahedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclopentane group is orientated in a transoid fashion with respect to the chloride ligand. The dihedral angle between the pryridine rings is 10.91 (12)°. In the crystal, N—H⋯Cl hydrogen bonds link complex molecules, forming a two-dimensional network parallel to (001).
AB - In the title compound, [ReCl(C15H16N4)(CO)3], the ReI ion is coordinated in a distorted octahedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclopentane group is orientated in a transoid fashion with respect to the chloride ligand. The dihedral angle between the pryridine rings is 10.91 (12)°. In the crystal, N—H⋯Cl hydrogen bonds link complex molecules, forming a two-dimensional network parallel to (001).
U2 - 10.1107/S1600536813023076
DO - 10.1107/S1600536813023076
M3 - Article
VL - 69
SP - m526
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 10
ER -