Tricarbonylchlorido(6′,7′-dihydro-5′H-spiro[cyclopentane- 1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine] -κ2 N 1,N 11)rhenium(I)

O.R. Clegg, L.P. Harding, J.W. Miller, C.R. Rice

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

In the title compound, [ReCl(C15H16N4)(CO)3], the ReI ion is coordinated in a distorted octa­hedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclo­pentane group is orientated in a transoid fashion with respect to the chloride ligand. The dihedral angle between the pryridine rings is 10.91 (12)°. In the crystal, N—H⋯Cl hydrogen bonds link complex mol­ecules, forming a two-dimensional network parallel to (001).
LanguageEnglish
Pagesm526
JournalActa Crystallographica Section E: Structure Reports Online
Volume69
Issue number10
DOIs
Publication statusPublished - Oct 2013

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Rhenium
Cyclopentanes
rhenium
Ligands
Atoms
ligands
pentanes
Dihedral angle
Carbon Monoxide
atoms
dihedral angle
Chlorides
Hydrogen bonds
chlorides
Ions
hydrogen bonds
Crystals
Geometry
rings
geometry

Cite this

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title = "Tricarbonylchlorido(6′,7′-dihydro-5′H-spiro[cyclopentane- 1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine] -κ2 N 1,N 11)rhenium(I)",
abstract = "In the title compound, [ReCl(C15H16N4)(CO)3], the ReI ion is coordinated in a distorted octa­hedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclo­pentane group is orientated in a transoid fashion with respect to the chloride ligand. The dihedral angle between the pryridine rings is 10.91 (12)°. In the crystal, N—H⋯Cl hydrogen bonds link complex mol­ecules, forming a two-dimensional network parallel to (001).",
author = "O.R. Clegg and L.P. Harding and J.W. Miller and C.R. Rice",
note = "cited By 1",
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TY - JOUR

T1 - Tricarbonylchlorido(6′,7′-dihydro-5′H-spiro[cyclopentane- 1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine] -κ2 N 1,N 11)rhenium(I)

AU - Clegg, O.R.

AU - Harding, L.P.

AU - Miller, J.W.

AU - Rice, C.R.

N1 - cited By 1

PY - 2013/10

Y1 - 2013/10

N2 - In the title compound, [ReCl(C15H16N4)(CO)3], the ReI ion is coordinated in a distorted octa­hedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclo­pentane group is orientated in a transoid fashion with respect to the chloride ligand. The dihedral angle between the pryridine rings is 10.91 (12)°. In the crystal, N—H⋯Cl hydrogen bonds link complex mol­ecules, forming a two-dimensional network parallel to (001).

AB - In the title compound, [ReCl(C15H16N4)(CO)3], the ReI ion is coordinated in a distorted octa­hedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclo­pentane group is orientated in a transoid fashion with respect to the chloride ligand. The dihedral angle between the pryridine rings is 10.91 (12)°. In the crystal, N—H⋯Cl hydrogen bonds link complex mol­ecules, forming a two-dimensional network parallel to (001).

U2 - 10.1107/S1600536813023076

DO - 10.1107/S1600536813023076

M3 - Article

VL - 69

SP - m526

JO - Acta Crystallographica Section E: Structure Reports Online

T2 - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 10

ER -