In the title compound, [ReCl(C15H16N4)(CO)3], the ReI ion is coordinated in a distorted octahedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclopentane group is orientated in a transoid fashion with respect to the chloride ligand. The dihedral angle between the pryridine rings is 10.91 (12)°. In the crystal, N—H⋯Cl hydrogen bonds link complex molecules, forming a two-dimensional network parallel to (001).
|Journal||Acta Crystallographica Section E: Structure Reports Online|
|Publication status||Published - Oct 2013|
Clegg, O. R., Harding, L. P., Miller, J. W., & Rice, C. R. (2013). Tricarbonylchlorido(6′,7′-dihydro-5′H-spiro[cyclopentane- 1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine] -κ2 N 1,N 11)rhenium(I). Acta Crystallographica Section E: Structure Reports Online, 69(10), m526. https://doi.org/10.1107/S1600536813023076