Unambiguous characterization of a photoreactive ligand-loss intermediate

Christine E. Welby, Craig R. Rice, Paul I P Elliott

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

Hanging in there: Unprecedented quantitative formation of a long-lived intermediate 2 that contains a monodentate N N ligand has been observed and the species characterized. Photoreactive ligand loss from a ruthenium(II) tris(chelate) complex 1 leads to 2, which has a half-life of 14 hours. Bn=benzyl.

LanguageEnglish
Pages10826-10829
Number of pages4
JournalAngewandte Chemie - International Edition
Volume52
Issue number41
DOIs
Publication statusPublished - 4 Oct 2013

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Ligands
Ruthenium

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Unambiguous characterization of a photoreactive ligand-loss intermediate. / Welby, Christine E.; Rice, Craig R.; Elliott, Paul I P.

In: Angewandte Chemie - International Edition, Vol. 52, No. 41, 04.10.2013, p. 10826-10829.

Research output: Contribution to journalArticle

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