Unambiguous characterization of a photoreactive ligand-loss intermediate

Christine E. Welby, Craig R. Rice, Paul I P Elliott

Research output: Contribution to journal › Article

25 Citations (Scopus)

Abstract

Hanging in there: Unprecedented quantitative formation of a long-lived intermediate 2 that contains a monodentate N N ligand has been observed and the species characterized. Photoreactive ligand loss from a ruthenium(II) tris(chelate) complex 1 leads to 2, which has a half-life of 14 hours. Bn=benzyl.

Original languageEnglish
Pages (from-to)10826-10829
Number of pages4
JournalAngewandte Chemie - International Edition
Volume52
Issue number41
DOIs
Publication statusPublished - 4 Oct 2013

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Ligands
Ruthenium

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Welby, Christine E. ; Rice, Craig R. ; Elliott, Paul I P. / Unambiguous characterization of a photoreactive ligand-loss intermediate. In: Angewandte Chemie - International Edition. 2013 ; Vol. 52, No. 41. pp. 10826-10829.
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Welby, CE, Rice, CR & Elliott, PIP 2013, 'Unambiguous characterization of a photoreactive ligand-loss intermediate', Angewandte Chemie - International Edition, vol. 52, no. 41, pp. 10826-10829. https://doi.org/10.1002/anie.201304219

Unambiguous characterization of a photoreactive ligand-loss intermediate. / Welby, Christine E.; Rice, Craig R.; Elliott, Paul I P.

In: Angewandte Chemie - International Edition, Vol. 52, No. 41, 04.10.2013, p. 10826-10829.

Research output: Contribution to journal › Article

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Welby CE, Rice CR, Elliott PIP. Unambiguous characterization of a photoreactive ligand-loss intermediate. Angewandte Chemie - International Edition. 2013 Oct 4;52(41):10826-10829. https://doi.org/10.1002/anie.201304219

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