Unambiguous characterization of a photoreactive ligand-loss intermediate

Christine E. Welby; Craig R. Rice; Paul I P Elliott

doi:10.1002/anie.201304219

Unambiguous characterization of a photoreactive ligand-loss intermediate

Christine E. Welby, Craig R. Rice, Paul I P Elliott

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29 Citations (Scopus)

Abstract

Hanging in there: Unprecedented quantitative formation of a long-lived intermediate 2 that contains a monodentate N N ligand has been observed and the species characterized. Photoreactive ligand loss from a ruthenium(II) tris(chelate) complex 1 leads to 2, which has a half-life of 14 hours. Bn=benzyl.

Original language	English
Pages (from-to)	10826-10829
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	41
DOIs	https://doi.org/10.1002/anie.201304219
Publication status	Published - 4 Oct 2013

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abstract = "Hanging in there: Unprecedented quantitative formation of a long-lived intermediate 2 that contains a monodentate N N ligand has been observed and the species characterized. Photoreactive ligand loss from a ruthenium(II) tris(chelate) complex 1 leads to 2, which has a half-life of 14 hours. Bn=benzyl.",

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AU - Elliott, Paul I P

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AB - Hanging in there: Unprecedented quantitative formation of a long-lived intermediate 2 that contains a monodentate N N ligand has been observed and the species characterized. Photoreactive ligand loss from a ruthenium(II) tris(chelate) complex 1 leads to 2, which has a half-life of 14 hours. Bn=benzyl.

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KW - photochemistry

KW - reactive intermediates

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KW - triazoles

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Unambiguous characterization of a photoreactive ligand-loss intermediate

Abstract

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