Abstract
Hanging in there: Unprecedented quantitative formation of a long-lived intermediate 2 that contains a monodentate N N ligand has been observed and the species characterized. Photoreactive ligand loss from a ruthenium(II) tris(chelate) complex 1 leads to 2, which has a half-life of 14 hours. Bn=benzyl.
| Original language | English |
|---|---|
| Pages (from-to) | 10826-10829 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 52 |
| Issue number | 41 |
| DOIs | |
| Publication status | Published - 4 Oct 2013 |
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Unambiguous characterization of a photoreactive ligand-loss intermediate. / Welby, Christine E.; Rice, Craig R.; Elliott, Paul I P.
In: Angewandte Chemie - International Edition, Vol. 52, No. 41, 04.10.2013, p. 10826-10829.Research output: Contribution to journal › Article
TY - JOUR
T1 - Unambiguous characterization of a photoreactive ligand-loss intermediate
AU - Welby, Christine E.
AU - Rice, Craig R.
AU - Elliott, Paul I P
PY - 2013/10/4
Y1 - 2013/10/4
N2 - Hanging in there: Unprecedented quantitative formation of a long-lived intermediate 2 that contains a monodentate N N ligand has been observed and the species characterized. Photoreactive ligand loss from a ruthenium(II) tris(chelate) complex 1 leads to 2, which has a half-life of 14 hours. Bn=benzyl.
AB - Hanging in there: Unprecedented quantitative formation of a long-lived intermediate 2 that contains a monodentate N N ligand has been observed and the species characterized. Photoreactive ligand loss from a ruthenium(II) tris(chelate) complex 1 leads to 2, which has a half-life of 14 hours. Bn=benzyl.
KW - monodentate ligands
KW - photochemistry
KW - reactive intermediates
KW - ruthenium
KW - triazoles
UR - http://www.scopus.com/inward/record.url?scp=84885148065&partnerID=8YFLogxK
U2 - 10.1002/anie.201304219
DO - 10.1002/anie.201304219
M3 - Article
AN - SCOPUS:84885148065
VL - 52
SP - 10826
EP - 10829
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 41
ER -