Unambiguous characterization of a photoreactive ligand-loss intermediate

Christine E. Welby, Craig R. Rice, Paul I P Elliott

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

Hanging in there: Unprecedented quantitative formation of a long-lived intermediate 2 that contains a monodentate N N ligand has been observed and the species characterized. Photoreactive ligand loss from a ruthenium(II) tris(chelate) complex 1 leads to 2, which has a half-life of 14 hours. Bn=benzyl.

Original languageEnglish
Pages (from-to)10826-10829
Number of pages4
JournalAngewandte Chemie - International Edition
Volume52
Issue number41
DOIs
Publication statusPublished - 4 Oct 2013

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