Unambiguous characterization of a photoreactive ligand-loss intermediate

Christine E. Welby; Craig R. Rice; Paul I P Elliott

doi:10.1002/anie.201304219

Unambiguous characterization of a photoreactive ligand-loss intermediate

Christine E. Welby, Craig R. Rice, Paul I P Elliott

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

Hanging in there: Unprecedented quantitative formation of a long-lived intermediate 2 that contains a monodentate N N ligand has been observed and the species characterized. Photoreactive ligand loss from a ruthenium(II) tris(chelate) complex 1 leads to 2, which has a half-life of 14 hours. Bn=benzyl.

Original language	English
Pages (from-to)	10826-10829
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	41
DOIs	https://doi.org/10.1002/anie.201304219
Publication status	Published - 4 Oct 2013

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title = "Unambiguous characterization of a photoreactive ligand-loss intermediate",

abstract = "Hanging in there: Unprecedented quantitative formation of a long-lived intermediate 2 that contains a monodentate N N ligand has been observed and the species characterized. Photoreactive ligand loss from a ruthenium(II) tris(chelate) complex 1 leads to 2, which has a half-life of 14 hours. Bn=benzyl.",

keywords = "monodentate ligands, photochemistry, reactive intermediates, ruthenium, triazoles",

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AU - Welby, Christine E.

AU - Rice, Craig R.

AU - Elliott, Paul I P

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N2 - Hanging in there: Unprecedented quantitative formation of a long-lived intermediate 2 that contains a monodentate N N ligand has been observed and the species characterized. Photoreactive ligand loss from a ruthenium(II) tris(chelate) complex 1 leads to 2, which has a half-life of 14 hours. Bn=benzyl.

AB - Hanging in there: Unprecedented quantitative formation of a long-lived intermediate 2 that contains a monodentate N N ligand has been observed and the species characterized. Photoreactive ligand loss from a ruthenium(II) tris(chelate) complex 1 leads to 2, which has a half-life of 14 hours. Bn=benzyl.

KW - monodentate ligands

KW - photochemistry

KW - reactive intermediates

KW - ruthenium

KW - triazoles

UR - https://www.scopus.com/pages/publications/84885148065

U2 - 10.1002/anie.201304219

DO - 10.1002/anie.201304219

M3 - Article

AN - SCOPUS:84885148065

SN - 1433-7851

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EP - 10829

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 41

ER -

Unambiguous characterization of a photoreactive ligand-loss intermediate

Abstract

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