Unexpected structural and electronic effects of internal rotation in diruthenium paddlewheel complexes containing bulky carboxylate ligands

Engineering & Materials Science

• Bond length 100%
• Density functional theory 33%
• Electrons 22%
• Ligands 89%
• Magnetic susceptibility 35%
• X ray crystallography 38%

Chemistry

• Bond Length 57%
• Bond Order 25%
• Density Functional Theory 13%
• Electron Particle 12%
• Energy 10%
• Internal Rotation 80%
• Ligand 29%
• Magnetic Susceptibility Measurement 23%
• Orbital 18%
• Shortening 25%
• X-Ray Crystallography 18%

Physics & Astronomy

• carboxylates 93%
• configurations 9%
• crystallography 19%
• density functional theory 12%
• electronics 34%
• electrons 7%
• energy 4%
• interactions 6%
• ligands 67%
• magnetic permeability 12%
• orbitals 11%
• x rays 7%